Observation of Rydberg blockade due to the charge-dipole interaction between an atom and a polar molecule [dataset]

We demonstrate Rydberg blockade due to charge-dipole interaction between a single Rb atom and a single RbCs molecule confined in optical tweezers. The molecule is formed by magnetoassociation of a Rb+Cs atom pair and subsequently transferred to the rovibrational ground state with an efficiency of 91(1)\%. Independent species-specific tweezers are used to control the separation between the atom and molecule. The charge-dipole interaction causes blockade of the transition to the Rb 52\,${^{2}\textrm{s}}_{1/2}$ Rydberg state, when the atom-molecule separation is set to $310(40)$~nm. The observed excitation dynamics are in good agreement with simulations using calculated interaction potentials. Our results open up the prospect of a hybrid platform where quantum information is transferred between individually trapped molecules using Rydberg atoms.