Formal Total Synthesis of (−)-Saliniketals
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https://figshare.com/articles/dataset/Formal_Total_Synthesis_of_Saliniketals/2811697
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资源简介：
A highly stereoselective formal total synthesis of the ornithine decarboxylase inhibitors (−)-saliniketals A and B is described. The salient features of the synthesis are the utilization of a desymmetrization technique to create six contiguous chiral centers from a single bicyclic precursor as well as substrate-controlled Grignard reaction, intramolecular Wacker-type oxidation, and antialdol reaction following Pirrung−Heathcock conditions.
创建时间：
2016-02-25
