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C−H versus C−N Bond Cleavage Promoted by Niobium(II) Amide

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/C_H_versus_C_N_Bond_Cleavage_Promoted_by_Niobium_II_Amide/3782457
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Despite their close structural similarity, the potassium and lithium salts of dipyridylamine and diphenylamine [(C5H5N)2N-, Ph2N-] react with (TMEDA)2Nb2Cl5Li(TMEDA) in THF to afford two different compounds arising from the cooperative oxidative addition of the two metal centers on either the C−H or C−N bond of the amide ligand.
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2016-08-27
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