Synthesis of Tertiary α-Hydroxy Acids by Silylene Transfer to α-Keto Esters
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https://figshare.com/articles/dataset/Synthesis_of_Tertiary_Hydroxy_Acids_by_Silylene_Transfer_to_Keto_Esters/2979214
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资源简介：
α-Keto esters can be converted into α-hydroxy acids in a single flask involving metal-catalyzed silylene transfer, 6π-electrocyclization, Ireland−Claisen rearrangement, and hydrolysis. This reaction sequence is stereoselective and tolerates alkyl- and aryl-substituted α-keto ester substrates
as well as an α-imino ester.
创建时间：
2016-06-03
