Synthesis of Tertiary α-Hydroxy Acids by Silylene Transfer to α-Keto Esters
收藏NIAID Data Ecosystem2026-03-06 收录
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α-Keto esters can be converted into α-hydroxy acids in a single flask involving metal-catalyzed silylene transfer, 6π-electrocyclization, Ireland−Claisen rearrangement, and hydrolysis. This reaction sequence is stereoselective and tolerates alkyl- and aryl-substituted α-keto ester substrates as well as an α-imino ester.
创建时间：
2016-06-03
