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Uncommon Ferromagnetic Interactions in a Homometallic Co(II) Chain Bridged by a Single End-to-End Azide

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NIAID Data Ecosystem2026-03-06 收录
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A new one-dimensional heterochiral coordination polymer [Co(bmdt)(N3)2]·MeCN (1·MeCN) with well-isolated chains was prepared via a self-assembly process. Magnetic data show that intrachain ferromagnetic couplings via the single end-to-end azide group are observed, which is an extraordinary case among the azide-bridged Co(II) systems.

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2016-06-03
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