Competition between sp<sup>3</sup>‑C–N vs sp<sup>3</sup>‑C–F Reductive Elimination from Pd<sup>IV</sup> Complexes
收藏NIAID Data Ecosystem2026-03-08 收录
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This communication describes the design of a model system that allows direct investigation of competing sp3-C–N and sp3-C–F bond-forming reductive elimination from a PdIV fluoro sulfonamide complex. The reductive elimination selectivity varies dramatically as a function of reaction additives. A mechanism is proposed that provides a rationale for these effects.
创建时间：
2014-03-19
