Facile Insertion of Rh and Ir into a Boron–Phenyl Bond, Leading to Boryl/Bis(phosphine) PBP Pincer Complexes
收藏NIAID Data Ecosystem2026-03-09 收录
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The unexpectedly facile insertion of Rh or Ir into a B–Ph bond (reversible for Rh) converts a borane/bis(phosphine) precursor into a boryl/bis(phosphine) PBP pincer ligand. Interconversions between the boryl/borane/borate central functionality are demonstrated in reactions with dihydrogen.
创建时间：
2016-01-29
