Hydrosilylation of Aldehydes and Ketones Catalyzed by Nickel PCP-Pincer Hydride Complexes
收藏NIAID Data Ecosystem2026-03-06 收录
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Nickel PCP-pincer hydride complexes catalyze chemoselective hydrosilylation of CO bonds of aldehydes and ketones in the presence of other functional groups. The mechanism involves CO insertion into a nickel−hydrogen bond, followed by cleavage of the newly formed Ni−O bond with a silane.
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2016-02-26
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