Visible Light Mediated, Redox Neutral Remote 1,6-Difunctionalizations of Alkenes
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https://figshare.com/articles/dataset/Visible_Light_Mediated_Redox_Neutral_Remote_1_6-Difunctionalizations_of_Alkenes/6531176
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资源简介:
A photoinduced
cascade strategy is presented here for the remote
functionalization of alkenes under redox neutral conditions. A broad
portfolio of alkyl groups has been added to double bonds to produce,
upon 1,5-HAT, remote C-centered radicals which can be harvested in
the presence of O- or C-nucleophiles to efficiently form Csp3–O and Csp3–Csp2 bonds at room
temperature.
创建时间:
2018-06-14



