Synthesis, Structural Characterization, and Reactivity of a Fluorene-Based Calcium Oxycyclopentadienide Complex
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https://figshare.com/articles/dataset/Synthesis_Structural_Characterization_and_Reactivity_of_a_Fluorene_Based_Calcium_Oxycyclopentadienide_Complex/2178004
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资源简介：
Direct
deprotonation of 9-fluorenol with Ca[N(SiMe3)2]2 efficiently generated a fluorene-based calcium
oxycyclopentadienide complex, which is the first alkaline earth metal
complex containing an oxycyclopentadienyl dianion ligand. The η5, η1, and η2 interactions
between the oxycyclopentadienyl dianion ligand and the calcium center
were observed in the solid state. The calcium oxycyclopentadienide
complex displayed reductive character and multiple reactive sites.
Its reactivity toward a range of electrophiles, especially acid chlorides,
was investigated and discussed in detail. A wide variety of fluorene
derivatives were synthesized.
创建时间：
2016-02-13
