Synthesis and Clathrates of Oligomeric 2-<i>O</i>-Naphthoide Macrocycles
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New macrocyclic O-naphthoides 4−6 were synthesized from dehydration reactions of 3-hydroxy- and 7-tert-butyl-3-hydroxy-2-naphthoic acids, respectively. Their X-ray structures were determined and their clathrate inclusion properties were investigated. Hexamer 6 formed an inclusion clathrate with four chloroform molecules. The trimer 5, by analogy with tri-o-thymotide, was studied for its potential optical resolution effects.
创建时间：
2011-02-04
