[Mn<sup>III</sup>Mn<sup>IV</sup><sub>2</sub>Mo<sub>14</sub>O<sub>56</sub>]<sup>17–</sup>: A Mixed-Valence Meso-Polyoxometalate Anion Encapsulated by a 64-Nuclearity Silver Cluster
收藏NIAID Data Ecosystem2026-03-09 收录
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A 64-nuclearity silver cluster encapsulating a unique POM anion [MnIIIMnIV2Mo14O56]17– has been synthesized. The formation of the templating core performs a reassembly process for increasing nuclearities from {MnMo9} to {Mn3Mo14}. It represents a rare inorganic meso anion containing mixed-valent Mn that is built up by d-{MnIVMo7} and l-{MnIVMo7} units connecting together through a {MnIII} fragment.
创建时间：
2016-07-12
