Trapping of an Ni<sup>II</sup> Sulfide by a Co<sup>I</sup> Fulvene Complex
收藏NIAID Data Ecosystem2026-03-10 收录
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The reaction of [LtBuNiII(SCPh3)] (LtBu = {(2,6-iPr2C6H3)NC(tBu)}2CH) with Cp*2Co yields a NiI cobaltocenium thiolate complex, [LtBuNiI(SCH2Me4C5)Co(Cp*)] (1), along with HCPh3. Formation of this complex is proposed to occur via the reaction of a transient NiII sulfide, [Cp*2Co][LtBuNiII(S)], with a CoI fulvene complex, [CoCp*(C5Me4CH2)]. The latter complex is formed in situ by reaction of [Cp*2Co]+ with [CPh3]−. Control experiments, as well as cyclic voltammetry measurements of 1, are used to support the proposed mechanism.
创建时间：
2017-04-20
