Steric Control between Neutral Metal-Only Lewis Pairs and Metal-Stabilized Gallenium and Gallinium Cations
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https://figshare.com/articles/dataset/Steric_Control_between_Neutral_Metal_Only_Lewis_Pairs_and_Metal_Stabilized_Gallenium_and_Gallinium_Cations/3145057
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资源简介:
Reaction of a series of zerovalent
Fe Lewis bases with Lewis acid
GaCl3 leads to both conventional, neutral metal-only Lewis
pairs in the case of small metal complexes and cationic gallenium
species in the case of larger metal bases. The results suggest the
predominance of steric bulk in controlling the outcome of group 13
trihalide Lewis acid additions to metal bases.
创建时间:
2016-04-05



