Pd(II)-Catalyzed Intermolecular Direct C–H Bond Iodination: An Efficient Approach toward the Synthesis of Axially Chiral Compounds via Kinetic Resolution
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https://figshare.com/articles/dataset/Pd_II_Catalyzed_Intermolecular_Direct_C_H_Bond_Iodination_An_Efficient_Approach_toward_the_Synthesis_of_Axially_Chiral_Compounds_via_Kinetic_Resolution/2269039
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资源简介:
An efficient protocol to synthesize
axially chiral compounds via
kinetic resolution by Pd(II)-catalyzed direct C–H iodination
was realized (up to s = 27). The iodide product could
be easily transformed to aryl-substituted pyridine N-oxides via the Suzuki–Miyaura coupling, which proved to be
a suitable catalyst in asymmetric allylation of benzaldehyde with
allyltrichlorosilane.
创建时间:
2016-02-17



