Reagent-Controlled α‑Selective Dehydrative Glycosylation of 2,6-Dideoxy Sugars: Construction of the Arugomycin Tetrasaccharide
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下载链接：
https://figshare.com/articles/dataset/Reagent-Controlled_Selective_Dehydrative_Glycosylation_of_2_6-Dideoxy_Sugars_Construction_of_the_Arugomycin_Tetrasaccharide/12117627
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资源简介：
The first synthesis of the tetrasaccharide
fragment of the anthracycline
natural product Arugomycin is described. A reagent controlled dehydrative
glycosylation method involving cyclopropenium activation was utilized
to synthesize the α-linkages with complete anomeric selectivity.
The synthesis was completed in 20 total steps, and in 2.5% overall
yield with a longest linear sequence of 15 steps.
创建时间：
2020-04-13
