Diastereoselective Construction of 7-Methylenebicyclo[3.2.1]oct-3-en-2-one Derivatives by Palladium-Catalyzed Cyclization of Propargylic Acetates with 2-Oxocyclohex-3-enecarboxylates
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https://figshare.com/articles/dataset/Diastereoselective_Construction_of_7_Methylenebicyclo_3_2_1_oct_3_en_2_one_Derivatives_by_Palladium_Catalyzed_Cyclization_of_Propargylic_Acetates_with_2_Oxocyclohex_3_enecarboxylates/2635723
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The reaction of propargylic acetates with 2-oxocyclohex-3-enecarboxylates in the presence of a palladium catalyst is described. Substituted 7-methylenebicyclo[3.2.1]oct-3-en-2-ones were synthesized in a highly diastereoselective manner.
创建时间:
2016-02-23



