Bimetallic Oxidative Addition in Nickel-Catalyzed Alkyl–Aryl Kumada Coupling Reactions
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https://figshare.com/articles/dataset/Bimetallic_Oxidative_Addition_in_Nickel_Catalyzed_Alkyl_Aryl_Kumada_Coupling_Reactions/2241745
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资源简介：
The
mechanism of alkyl–aryl Kumada coupling catalyzed by
the nickel pincer complex Nickamine was studied. Experiments using
radical-probe substrates and DFT calculations established a bimetallic
oxidative addition mechanism. Kinetic measurements showed that transmetalation
rather than oxidative addition was the turnover-determining step.
The transmetalation involved a bimetallic pathway.
创建时间：
2014-10-27
