Metal-Free Decarboxylative Cyanomethylation of β‑Aryl/Heteroaryl Substituted α,β-Unsaturated Carboxylic Acids to γ‑Ketonitriles
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https://figshare.com/articles/dataset/Metal-Free_Decarboxylative_Cyanomethylation_of_Aryl_Heteroaryl_Substituted_-Unsaturated_Carboxylic_Acids_to_Ketonitriles/27651765
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资源简介：
A decarboxylative cyanomethylation of β-aryl/heteroaryl
substituted
α,β-unsaturated carboxylic acids has been accomplished
via C(sp3)-H activation of alkyl nitriles to afford diverse
γ-ketonitriles by making use of 1,8-diazabicyclo[5.4.0]undec-7-ene
(DBU) and tert-butyl hydroperoxide (TBHP). The present
report offers a metal-free approach and is featured with a broad substitution
pattern and functional group compatibility.
创建时间：
2024-11-11
