Ten-Step Total Synthesis of (−)-Andranginine
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https://figshare.com/articles/dataset/Ten-Step_Total_Synthesis_of_-Andranginine/21122808
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资源简介：
The
total synthesis of the indole alkaloid (−)-andranginine
has been achieved in 10 steps. Key reactions of the synthesis include
a nucleophilic addition of acetylenyl anion to chiral N-sulfinyl imine, an intramolecular N-alkylation
reaction to close the C ring, and a dienyne metathesis cascade reaction
to construct the DE rings. Meanwhile, 16-epi-(−)-andranginine
was also obtained with the developed strategy.
创建时间：
2022-09-13
