A Novel Coordination Mode for Pentalene in Trinuclear Chromium Complexes
收藏NIAID Data Ecosystem2026-03-06 收录
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The first chromium pentalene complexes have been characterized; in these the ligand displays a hitherto-unknown bonding mode whereby a dimeric [Cr(Cp*)]2(μ-OR) unit is bound (μ:η2:η2)- to one face, and Cp*Cr is bound η5- to the other. The magnetic properties of these compounds can be understood as the superposition of those of a chromocene and an antiferromagnetically coupled Cr−Cr bonded unit.
创建时间：
2016-05-07
