The Mechanism of Hydrogen Activation by NiFe-hydrogenases
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The Mechanism of Hydrogen Activation by NiFe-hydrogenases
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2024-11-06
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A Digermyne with a Ge–Ge Single Bond That Activates Dihydrogen in the Solid State
The reduction of the bulky amido-germanium(II) chloride complex, LGeCl (L = N(SiMe3)(Ar*); Ar* = C6H2Me{C(H)Ph2}2-4,2,6), with the magnesium(I) dimer, [{(MesNacnac)Mg}2] (MesNacnac = [(MesNCMe)2CH]−;
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Reversible H2 Addition across a Nickel–Borane Unit as a Promising Strategy for Catalysis
We report the synthesis and characterization of a series of nickel complexes of the chelating diphosphine-borane ligands ArB(o-Ph2PC6H4)2 ([ArDPBPh]; Ar = Ph, Mes). The [ArDPBPh] framework supports p
Figshare2016-02-21 更新40
A Digermyne with a Ge–Ge Single Bond That Activates Dihydrogen in the Solid State
The reduction of the bulky amido-germanium(II) chloride complex, LGeCl (L = N(SiMe3)(Ar*); Ar* = C6H2Me{C(H)Ph2}2-4,2,6), with the magnesium(I) dimer, [{(MesNacnac)Mg}2] (MesNacnac = [(MesNCMe)2CH]−;
Figshare2016-02-22 更新30
Dihydrogen Activation by Cobaloximes with Various Axial Ligands
We have investigated the effect of axial ligands on the ability of cobaloximes to catalyze the generation of transferable hydrogen atoms from hydrogen gas and have learned that the active catalyst con
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Heterolytic Cleavage of Dihydrogen by an Iron(II) PNP Pincer Complex via Metal–Ligand Cooperation
The bis-carbonyl Fe(II) complex trans-[Fe(PNP-iPr)(CO)2Cl]+ reacts with Zn as reducing agent under a dihydrogen atmosphere to give the Fe(II) hydride complex cis-[Fe(PNP-iPr)(CO)2H]+ in 97% isol
Figshare2015-12-16 更新30
