Heptamethyl Indenyl (Ind*) Enables Diastereoselective Benzamidation of Cyclopropenes via Rh(III)-Catalyzed C-H Activation

NIAID Data Ecosystem2026-03-11 收录

C-H键活化催化

环丙烯苯甲酰胺化

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Supporting Information: DFT optimised structures as described in the title paper

创建时间：

2020-01-24

Direct Observation of C–H Cyclopalladation at Tertiary Positions Enabled by an Exo-Directing Group

有机金属化学

C-H键活化催化

Here we describe the first preparation of tertiary alkyl palladium complexes via C–H activation. Enabled by an exo-type oxime directing group, cyclopalladation occurred smoothly at the bridgehead posi

NIAID Data Ecosystem80

Selective C–C and C–H Bond Activation/Cleavage of Pinene Derivatives: Synthesis of Enantiopure Cyclohexenone Scaffolds and Mechanistic Insights

C-H键活化催化

天然产物合成骨架

The continued development of transition-metal-mediated C–C bond activation/cleavage methods would provide even more opportunities to implement novel synthetic strategies. We have explored the Rh(I)-c

NIAID Data Ecosystem50

C–H Activation of Terminal Alkynes by Tris-(3,5-dimethylpyrazolyl)boraterhodiumneopentylisocyanide: New Metal–Carbon Bond Strengths

C-H键活化催化

化学键能计算

C–H bond activation of terminal alkynes by [Tp′Rh(CNneopentyl)] (Tp′ = hydridotris-(3,5-dimethylpyrazolyl)borate) resulted in the formation of terminal C–H bond activation products Tp′Rh(CNneopenty

Figshare2016-02-20 更新20

Ir-Catalyzed Cascade C–H Fusion of Aldoxime Ethers and Heteroarenes: Scope and Mechanisms

C-H键活化催化

杂环芳烃合成

A concise synthesis of phenanthridine derivatives is achieved by an iridium-catalyzed direct fusion of oxime ethers and heteroarenes, which is a successful example of a cascade C–H/C–H cross-coupling/

NIAID Data Ecosystem80

C–H Activation/Functionalization Catalyzed by Simple, Well-Defined Low-Valent Cobalt Complexes

C-H键活化催化

氢芳基化反应

A facile C–H activation and functionalization of aromatic imines is presented using low-valent cobalt catalysts. Using Co(PMe3)4 as catalyst we have developed an efficient and simple protocol for the

NIAID Data Ecosystem30

Heptamethyl Indenyl (Ind*) Enables Diastereoselective Benzamidation of Cyclopropenes via Rh(III)-Catalyzed C-H Activation

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