Catalytic α‑Monoallylation of Aryl Acetonitriles
收藏NIAID Data Ecosystem2026-03-09 收录
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资源简介：
α-Cyano aldehydes undergo selective transition-metal-catalyzed monoallylation to provide α-allylated nitriles. The transformation leads to linear substitution products with palladium catalysts or branched allylated nitriles using an iridium catalyst. Facile TBD-catalyzed retro-Claisen cleavage is leveraged to attain selective monoallylation.
创建时间：
2016-02-16
