Bis(phosphine)cobalt Dialkyl Complexes for Directed Catalytic Alkene Hydrogenation
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https://figshare.com/articles/dataset/Bis_phosphine_cobalt_Dialkyl_Complexes_for_Directed_Catalytic_Alkene_Hydrogenation/2252221
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资源简介：
Planar, low-spin
cobalt(II) dialkyl complexes bearing bidentate
phosphine ligands, (P–P)Co(CH2SiMe3)2, are active for the hydrogenation of geminal and 1,2-disubstituted
alkenes. Hydrogenation of more hindered internal and endocyclic trisubstituted
alkenes was achieved through hydroxyl group activation, an approach
that also enables directed hydrogenations to yield contrasteric isomers
of cyclic alkanes.
创建时间：
2014-09-24
