Three-Dimensional Lanthanide Anionic Metal−Organic Frameworks with Tunable Luminescent Properties Induced by Cation Exchange
收藏NIAID Data Ecosystem2026-03-06 收录
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Three 3D lanthanide anionic metal−organic frameworks {K5[Ln5(IDC)4(ox)4]}n·(20H2O)n with 1D channels were synthesized under hydrothermal conditions [Ln = Gd (1), Tb (2), and Dy (3)]. The K+ ions within the 1D channel are easily exchanged with various cations. The emission intensities of TbIII in 2 increased significantly upon the addition of Ca2+ ions, while the introduction of other metal ions caused the intensities to be either unchanged or weakened.
创建时间：
2016-02-26
