Porphyrin–Hexaphenylbenzene Conjugates via Mixed Cyclotrimerization Reactions
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https://figshare.com/articles/dataset/Porphyrin_Hexaphenylbenzene_Conjugates_via_Mixed_Cyclotrimerization_Reactions/7571957
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资源简介：
Mixed cyclotrimerization reactions
of diarylacetylenes (tolans)
were applied to generate a library of multiple porphyrin–hexaphenylbenzene
(HPB) architectures. Successful reactions, which could be influenced
by the ratio of tolan starting materials, were conducted using dicobaltoctacarbonyl
as a catalyst. Separation of the reaction products was performed by
chromatographic and crystallization techniques. The physical properties
were investigated with respect to the number of porphyrins per HPB
and their substitution pattern.
创建时间：
2019-01-10
