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Insertion of Zerovalent Nickel into the N–N Bond of N‑Heterocyclic-Carbene-Activated N2O

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Figshare2016-02-18 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Insertion_of_Zerovalent_Nickel_into_the_N_N_Bond_of_N_Heterocyclic_Carbene_Activated_N_sub_2_sub_O/2364583
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资源简介:
Metal-mediated cleavage of the N–N bond is a rarely observed phenomenon in the chemistry of nitrous oxide (N2O). We demonstrate that, upon activation of N2O with N-heterocyclic carbenes, zerovalent nickel is able to insert into the N–N bond to give nitrosyl complexes.
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2016-02-18
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