Synthesis and Catalytic Activity of Molybdenum–Dinitrogen Complexes Bearing Unsymmetric PNP-Type Pincer Ligands
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https://figshare.com/articles/dataset/Synthesis_and_Catalytic_Activity_of_Molybdenum_Dinitrogen_Complexes_Bearing_Unsymmetric_PNP_Type_Pincer_Ligands/2461933
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Novel dinitrogen-bridged dimolybdenum complexes bearing unsymmetric PNP-type pincer ligands are prepared and characterized by X-ray analysis. A molybdenum–dinitrogen complex bearing 2-(di-1-adamantylphosphino)methyl-6-(di-tert-butylphosphino)methylpyridine has been found to work as an effective catalyst toward the formation of ammonia from molecular dinitrogen under ambient conditions.
创建时间：
2016-02-20
