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Gold(I)-Catalyzed Intra- and Intermolecular Alkenylations of β‑Yne-pyrroles: Facile Formation of Fused Cycloheptapyrroles and Functionalized Pyrroles

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Figshare2016-02-17 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Gold_I_Catalyzed_Intra_and_Intermolecular_Alkenylations_of_Yne_pyrroles_Facile_Formation_of_Fused_Cycloheptapyrroles_and_Functionalized_Pyrroles/2304994
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An efficient gold­(I)-catalyzed alkenylation of β-alkyne-substituted pyrroles is reported. The intramolecular reaction gives straightforward access to different types of seven-membered-ring-fused pyrroles with endo-selectivity, and the intermolecular reaction with alkynes provides functionalized pyrrole derivatives.
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2016-02-17
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