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Slow Magnetization Relaxation in NiIIDyIIIFeIII Molecular Cycles

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Figshare2016-02-14 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Slow_Magnetization_Relaxation_in_Ni_sup_II_sup_Dy_sup_III_sup_Fe_sup_III_sup_Molecular_Cycles/2196346
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Two cyano- and phenoxo-bridged hexanuclear NiII2DyIII2FeIII2 (1) and octanuclear NiII4DyIII2FeIII2 (2) trimetallic cyclic complexes have been obtained. They are the first trimetallic metallocycles. Magnetic studies reveal that 1 and 2 exhibit single-molecule-magnet behavior with an energy barrier of 17.9 K for complex 1 in a 2000 Oe static field and 25.0 K for complex 2 in a zero static field.
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2016-02-14
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