Rapid Assembly of the Polyhydroxylated β-Amino Acid Constituents of Microsclerodermins C, D, and E
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https://figshare.com/articles/dataset/Rapid_Assembly_of_the_Polyhydroxylated_Amino_Acid_Constituents_of_Microsclerodermins_C_D_and_E/2953459
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资源简介：
A very short and efficient synthesis of protected derivatives of APTO and AETD, the complex polyhydroxylated β-amino acid residues present
in microsclerodermins C, D, and E, is described. The targets are obtained in only five steps, in 23% and 16% overall yields, respectively. The
key transformation involves the completely diastereoselective two-carbon homologation of appropriately selected intermediate chiral sulfinimines.
创建时间：
2016-06-03
