Structure and Properties of Neutral and Cationic Gold(III) Complexes from Substituted 2‑(2′-Pyridyl)quinoline Ligands
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https://figshare.com/articles/dataset/Structure_and_Properties_of_Neutral_and_Cationic_Gold_III_Complexes_from_Substituted_2_2_Pyridyl_quinoline_Ligands/2230585
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资源简介：
A one-step
catalytic synthesis of 6-substituted 4-phenyl-2-(2′-pyridyl)quinolines
provides electronically differentiated ligands without solvent, inert
atmosphere, metal contamination, or chromatography. Gold(III) complexes
formed from these bidentate PyQuin ligands were characterized and
studied by single-crystal X-ray diffraction. The cationic gold(III)
chloride synthesized from 6-methoxy-4-phenyl-2-(2′-pyridyl)quinoline
has a distorted square-planar ligand environment. Diamagnetic neutral
gold(III) complexes from methoxy-, methyl-, and phenyl-PyQuin ligands
exhibit a long axial Au–N2 interaction.
创建时间：
2014-12-01
