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Nickel(0) Complexes of a 1-Zirconacyclopent-3-yne

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https://figshare.com/articles/dataset/Nickel_0_Complexes_of_a_1_Zirconacyclopent_3_yne/3281410
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资源简介:
The complexation of the uncommon 1-zirconacyclopent-3-yne Cp2Zr(η4-H2C4H2) by Ni(0) complexes is described and compared to the coordination of similar 1-metallacyclopenta-2,3,4-trienes Cp2M(η4-PhC4Ph) of titanium and zirconium, both showing μ-“cis”-complexation of 1,2,3-butatrienes and 1,3-butadiynes in addition to the well-known μ-“trans”-complexation.
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2005-06-20
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