Rare Examples of Fe(IV) Alkyl-Imide Migratory Insertions: Impact of FeC Covalency in (Me2IPr)Fe(NAd)R2 (R = neoPe, 1‑nor)

Figshare2017-08-25 更新2026-04-29 收录

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https://figshare.com/articles/dataset/Rare_Examples_of_Fe_IV_Alkyl-Imide_Migratory_Insertions_Impact_of_Fe_C_Covalency_in_Me_sub_2_sub_IPr_Fe_NAd_R_sub_2_sub_R_sup_neo_sup_Pe_1_nor_/5349118

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The iron(IV) imide complexes, (Me2IPr)–R2Fe=NAd (R = neoPe (3a), 1-nor (3b)) undergo migratory insertion to iron(II) amides (Me2IPr)RFe{NR(Ad)} (R = neoPe (4a), 1-nor (4b)) without evidence of imidyl or free nitrene character. By increasing the field strength about iron, odd-electron reactivity was circumvented via increased covalency.

创建时间：

2017-08-25