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Highly Selective FeCl3‑Catalyzed Cyclization of β‑Sulfonamidoallenes or β‑Allenols and Aldehydes

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Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Highly_Selective_FeCl_sub_3_sub_Catalyzed_Cyclization_of_Sulfonamidoallenes_or_Allenols_and_Aldehydes/2426494
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资源简介:
A FeCl3-catalyzed Prins cyclization reaction of β-sulfonamidoallenes or β-allenols with aldehydes has been developed for the synthesis of 3-chloromethyl-1,2,5,6-tetrahydro-1H-pyridine or 3-chloromethyl-5,6-dihydro-2H-pyran. The reaction is highly selective due to the stability of the allyl cation intermediate.
创建时间:
2016-02-19
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