Regiospecific C–H Bond Activation: Reactivity Study of N-Heterocyclic Silylene toward Ambidentate Phosphorus Ylide
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https://figshare.com/articles/dataset/Regiospecific_C_H_Bond_Activation_Reactivity_Study_of_N_Heterocyclic_Silylene_toward_Ambidentate_Phosphorus_Ylide/2643127
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资源简介：
The reaction of two highly reactive species, the silylene [CH{C(Me)NAr}{C(CH2)NAr}Si] (L, Ar = 2,6-iPr2C6H3) and the phosphorus ylide MeC(O)CHPPh3, resulted in the formation of 1, involving regiospecific Calkyl–H bond activation. Compound 1 was characterized by elemental analysis and multinuclear NMR and unambiguously by single-crystal X-ray structural analysis.
创建时间：
2011-06-13
