Luminescent Cyclometalated Platinum Complexes with π‑Bonded Catecholate Organometallic Ligands
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https://figshare.com/articles/dataset/Luminescent_Cyclometalated_Platinum_Complexes_with_Bonded_Catecholate_Organometallic_Ligands/4639732
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资源简介：
A series of cyclometalated
platinum(II) complexes of the type [(ppy)Pt(LM)]n+ (n = 0, 1) with π-bonded
catecholates acting as organometallic ligands (LM) have
been prepared and characterized by analytical techniques. In addition,
the structures of two complexes of the series were determined by single-crystal
X-ray diffraction. The packing shows the formation of a 1D supramolecular
assembly generated by dPt–πCp* interactions
among individual units. All complexes are luminescent in the solid
state and in solution media. The results of photophysics have been
rationalized by means of density functional theory (DFT) and time-dependent
DFT investigations.
创建时间：
2017-02-09
