A Single-Molecule Magnet Based on Heptacyanomolybdate with the Highest Energy Barrier for a Cyanide Compound
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Three trinuclear Mn2Mo molecules based on the orbitally degenerate [Mo(CN)7]4– anion were prepared, one of which is the first single-molecule magnet (SMM) based on heptacyanomolybdate. The blocking temperature and the energy barrier (U = 40.5 cm–1) are records for a cyanide-based SMM. Wide hysteresis loops and sharp quantum tunneling steps were observed from single-crystal measurements.
创建时间：
2016-02-18
