Enantioselective Synthesis of Planar Chiral Ferrocenes via Pd(0)-Catalyzed Intramolecular Direct C–H Bond Arylation
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https://figshare.com/articles/dataset/Enantioselective_Synthesis_of_Planar_Chiral_Ferrocenes_via_Pd_0_Catalyzed_Intramolecular_Direct_C_H_Bond_Arylation/2310439
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资源简介：
A highly
efficient synthesis of planar chiral ferrocenes by enantioselective
Pd(0)-catalyzed direct C–H arylation from readily available
starting materials under mild reaction conditions was developed (up
to 99% yield, 99% ee). The products can be easily transformed to the
highly efficient planar ferrocene ligands, which have demonstrated
high efficiency in Pd-catalyzed asymmetric allylic alkylation and
amination reactions.
创建时间：
2014-04-02
