Exploring the Uranyl Organometallic Chemistry: From Single to Double Uranium−Carbon Bonds
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https://figshare.com/articles/dataset/Exploring_the_Uranyl_Organometallic_Chemistry_From_Single_to_Double_Uranium_Carbon_Bonds/2659120
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Uranyl organometallic complexes featuring uranium(VI)−carbon single and double bonds have been obtained from uranyl UO2X2 precursors by avoiding reduction of the metal center. X-ray diffraction and density functional theory analyses of these complexes showed that the U−C and UC bonds are polarized toward the nucleophilic carbon.
创建时间：
2016-02-23
