Synthesis of Highly Functionalized 9,10-Phenanthrenequinones by Oxidative Coupling Using MoCl5
收藏Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthesis_of_Highly_Functionalized_9_10_Phenanthrenequinones_by_Oxidative_Coupling_Using_MoCl_sub_5_sub_/2513383
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资源简介:
The strong oxidative power of molybdenum pentachloride gives rise to an efficient oxidative C–C bond formation of benzil derivatives to the corresponding 9,10-phenanthrenequinones. A highly complementary method to previous approaches was developed. The required derivatives are accessible in a modular fashion and in excellent yields. By this approach the orchid-derived natural product cypripediquinone A was synthesized for the first time.
创建时间:
2016-02-20



