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Regioselective Metalation of a Tertiary Phosphine. Solution and Solid-State Structures of an Unusual Aminobenzyllithium Complex

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Regioselective_Metalation_of_a_Tertiary_Phosphine_Solution_and_Solid-State_Structures_of_an_Unusual_Aminobenzyllithium_Complex/3785472
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资源简介:
Metalation of the tertiary phosphine MeP(C6H4-2-CH2NMe2)2 with t-BuLi proceeds exclusively to give the novel dimeric benzyllithium complex [MeP(C6H4-2-CH2NMe2){C6H4-2-CH(Li)NMe2}]2; variable-temperature NMR studies show that this complex undergoes a novel dynamic process in solution.
创建时间:
2016-08-27
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