Heterometallic 3d–4f Coordination Polymers Based on 1,4,7-Triazacyclononane-1,4,7-triyl-tris(methylenephosphonate)
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https://figshare.com/articles/dataset/Heterometallic_3d_4f_Coordination_Polymers_Based_on_1_4_7_Triazacyclononane_1_4_7_triyl_tris_methylenephosphonate_/2282383
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资源简介：
Five
heterometallic 3d–4f coordination polymers based on
1,4,7-triazacyclononane-1,4,7-triyl-tris(methylenephosphonic acid)
(notpH6) are reported. Compounds [FeLn(notpH)(H2O)4]ClO4·5H2O [Ln = Nd (FeNd), Gd (FeGd), Sm (FeSm), Eu
(FeEu)] are isostructural. All show layer structures
in which the Fe(notpH)2– unit serves as a metalloligand
to link four equivalent LnIII ions into a layer. Compound
[CuLa(notpH2)(H2O)2]ClO4·3H2O (CuLa) displays a chain structure,
where the Cu(notpH2)2– unit connects
the LaIII ions into a chain. The magnetic properties of FeLn are studied.
创建时间：
2014-06-16
