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Construction of Heteroacenes with Fused Thiophene and Pyrrole Rings via the Fischer Indolization Reaction

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NIAID Data Ecosystem2026-03-09 收录
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https://figshare.com/articles/dataset/Construction_of_Heteroacenes_with_Fused_Thiophene_and_Pyrrole_Rings_via_the_Fischer_Indolization_Reaction/2078158
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A convenient approach to ladder-type 6H-benzo­[4′,5′]­thieno­[2′,3′:4,5]­thieno­[3,2-b]­indoles bearing various substituents in both terminal benzene rings has been developed. The protocol suggested for preparing these N,S-heteroacenes is based on using easily available reagents, such as cinnamic acids and arylhydrazines, which can be involved in the Fischer indole synthesis, as the key step. A similar condensed system of 12H-benzo­[4″,5″]­thieno­[2″,3″:4′,5′]­thieno­[2′,3′:4,5]­thieno­[3,2-b]­indole, bearing six rings, has also been obtained.
创建时间:
2016-02-12
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