Interrupting the Nazarov Cyclization with Bromine
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https://figshare.com/articles/dataset/Interrupting_the_Nazarov_Cyclization_with_Bromine/4289831
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资源简介：
The generation of dibrominated cyclopentenones
via an interrupted
Nazarov cyclization is reported. The installation of two bromine atoms
occurs at the α and α′ positions of the cyclopentenyl
scaffold via successive nucleophilic and electrophilic bromination
of the 2-oxidocyclopentenyl cation and its resulting enolate. Notably,
the reaction proceeds with good diastereoselectivity, favoring the
symmetrical product.
创建时间：
2016-12-06
