Enantioselective Intramolecular Aldehyde α‑Alkylation with Simple Olefins: Direct Access to Homo-Ene Products
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https://figshare.com/articles/dataset/Enantioselective_Intramolecular_Aldehyde_Alkylation_with_Simple_Olefins_Direct_Access_to_Homo_Ene_Products/2401906
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资源简介：
A highly
selective method for the synthesis of asymmetrically substituted carbocycles
and heterocycles from unactivated aldehyde–olefin precursors
has been achieved via enantioselective SOMO-catalysis. Addition of
a catalytically generated enamine radical cation across a pendent
olefin serves to establish a general asymmetric strategy toward the
production of a wide range of formyl-substituted rings with alkene
transposition. Conceptually, this novel mechanism allows direct access
to “homo-ene”-type products.
创建时间：
2016-02-19
