Engaging Two Anions with Single Cation in Energetic Salts: Approach for Optimization of Oxygen Balance in Energetic Materials

The field of high energy density materials faces a long-standing challenge to achieve an optimum balance between energy and stability. While energetic salt formation via a combination of oxygen- and nitrogen-rich anions (providing energy) with nitrogen-containing cations (providing stability) has been a proven approach for improving physical stability, constraints such as lowering density and energetic performance remain unresolved. This can be addressed by utilizing oxygen-containing cations for salt formation. However, this approach is rarely explored because its synthesis is challenging. In this work, we have designed an oxygen-rich cationic precursor 2 by incorporating 4-amino-3,5-dinitropyrazole with 3,4-diaminotriazole via an N-methylene-C bridge. Further combination with energetic acids resulted in the formation of high-performing, physically stable energetic salts 3–10. The salts were found to be generally more energetic than the salts of respective energetic acids with previously reported cations and showed prominent improvement in physical stability with respect to their anionic precursors. All the compounds were thoroughly characterized through IR, NMR spectroscopy, HRMS, and elemental analysis. Salt 9 was confirmed through 15N NMR analysis, and salts 2 and 8 were confirmed through single-crystal X-ray diffraction. Additional analyses such as Hirshfeld surface analysis, noncovalent interaction (NCI) analysis, and electrostatic potential studies were also carried out to correlate the structure–property relationship.