Synthesis of <i>N</i>‑Acylamidines via Rhodium-Catalyzed Reaction of Nitrosobenzene Derivatives with <i>N</i>‑Sulfonyl-1,2,3-triazoles
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资源简介：
α-Imino rhodium carbene, readily generated from N-sulfonyl-1,2,3-triazole, underwent cycloaddition and subsequent rearrangement with a nitrosobenzene derivative to afford N-acylamidine. The unprecedented C–C bond cleavage of α-imino carbene was facilitated by the weakness of the N–O bond.
创建时间：
2016-02-16
